Turbulent One-dimensional Interfacial Scalar Transport: Statistical Random Square Waves Solution

Document Type : Regular Article

Authors

1 Hydro-Engineering Solutions (Hydro LLC), Auburn, Alabama, 36830, USA

2 University of São Paulo (EESC-USP), São Carlos, São Paulo, 13566-590, Brazil

3 Faculty of Engineering, University of Bio Bio,Concepción , Chile

Abstract

In this study the mass transport through free turbulent liquid surfaces, or gas/liquid interfaces, is considered. The main direction of mass transfer is perpendicular to the interface, so that a one-dimensional point of view is followed. The equations for the interfacial gas/liquid transport are presented using the random square waves method (RSW), a statistical tool that models the fluctuations of physical variables as ideal signals. The method defines three statistical functions (partition, reduction, and superposition), related to fluctuations of concentration and velocity, which were introduced into the mass advection-diffusion equation generating a set of differential equations adequate for boundary layer problems. Solution profiles of the partition and reduction functions, and of turbulent fluxes across the boundary layer were obtained for transient situations. The solutions use Taylor series centered at the immersed border of the concentration boundary layer. For practical applications, the series were truncated and the coefficients were calculated in order to satisfy adequate physical conditions. The proposed procedure substitutes coefficients of the higher order parcels of the truncated series, enabling them to satisfy boundary conditions in the two borders of the domain of interest, which is the region of variation of the mass concentration. The theoretical profiles for concentration and turbulent fluxes close to the interface agree with measurements and predictions found in the literature.
 

Keywords


Asano, K. (2006). Mass Transfer: From Fundamentals to Modern Industrial Applications. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Germany.##
Bennett, J. P. and R. E. Rathbun (1971). Reaeration in Open-Channel Flow. US Department of the Interior, Geological Survey.##
Bongo, D., N. D. Clarisse and J. Y. Champagne (2021). Effect of an oscillating grid on hydrodynamics and gas-liquid mass transfer in an aquarium. Fluid Mechanics 7(1), 9-16.##
Boyadjiev, C. and P. Mitev (1977). On the concentration boundary layer theory at a moving interface. The Chemical Engineering Journal 14(3), 225-228.##
Brumley, B. (1984). Turbulence measurements near the free surface in stirred grid experiments. In W. Brutsaert and G. H. Jirka (Eds), Gas Transfer at Water Surfaces. Water Science and Technology Library, 2, 83-92. Springer, Dordrecht.##
Brumley, B; G.H. Jirka (1987). Near-surface turbulence in a grid-stirred tank. Journal of Fluid Mechanics, 183, 235-263.##
Brumley, B. and G. H. Jirka (1988). Air-water transfer of slightly soluble gases: turbulence, interfacial processes and conceptual models. Physico-Chemical Hydrodynamics 10(3), 295-319.##
Chu, C. R. and G. H. Jirka (1992). Turbulent gas flux measurements below the air-water interface of a grid-stirred tank. International Journal of Heat and Mass Transfer 35(8), 1957-1968.##
Cunha, A. C., D. C. Brito, H. F. A. Cunha and H. E. Schulz (2011). Dam Effect on Stream Reaeration Evaluated with the Qual 2kw Model: Case Study of the Araguari River, Amazon Region, Amapá State/Brazil. In C. Bilibio, O. Hensel and J. Selbach (Eds.), Sustainable Water Management in the Tropics and Subtropics-and Case Studies in Brazil. 1ed.Kassel: Unikassel, 2, 153-177.##
Danckwerts, P. V. (1951). Significance of liquid-film coefficients in gas absorption. Industrial & Engineering Chemistry 43, 1460-1467.##
Donelan, M. A., W. M. Drennan., E. S. Saltzman and R. Wanninkhof (2002). Gas transfer at water surfaces. Geophysical Monograph Series 127.American Geophysical Union.##
EPA Environmental Protection Agency (1995). QUAL2E Windows Interface User’s Manual, EPA-823-95-003, Office of Water, U.S.A.##
Flagiello, D., A. Parisi, A. Lancia and F. Di Natale (2021). A review on gas-liquid mass transfer coefficients in packed-bed columns. Chem Engineering 43(5), 1-29.##
Friedl, F. (2013) Investigating the Transfer of Oxygen at the Wavy Air-Water Interface Under Wind-Induced Turbulence. Ph. D. Thesis, University of Heidelberg, Heidelberg, Germany.##
Gonçalves, B. B. (2014). Detailing the 1-D solution of the RSW Method Taking a Constant Reduction Function for the Turbulent Interfacial Scalar Transport (in Portuguese). M. Sc. Thesis, University of São Paulo, Brazil.##
Gonçalves, B. B. and H. E. Schulz (2013) One-dimen-sional turbulent mass transfer at air-water inter-faces: details of discontinuities of derivatives using the RSW method. WIT Transactions on Engineering Sciences 79, 365-376.##
Gulliver, J. S. (1991). Introduction to air-water mass transfer. In Proceedings of the 2nd International Symposium on Gas Transfer at Water Surfaces, Minneapolis, USA, ASCE.##
Herlina, H. (2005). Gas Transfer at the Air-Water Inter-Face in A Turbulent Flow Environment. Ph. D. Thesis, University of Karlsruhe, Karlsruhe, Germany.##
Herlina, H. and G. H. Jirka (2004). Application of LIF to investigate gas transfer near the air-water interface in a grid-stirred tank. Experiments in Fluids 37(3), 341-349.##
Herlina, H. and G. H. Jirka (2007). Experiments on gas transfer at the air–water interface induced by oscillating grid turbulence. Journal of Fluid Mechanics 594, 183-208.##
Herlina, H. and J. G. Wissink (2019). Simulation of air–water interfacial mass transfer driven by high-intensity isotropic turbulence. Journal of Fluid Mechanics 860, 419-440.##
Higbie, R. (1935). The rate of absorption of a pure gas into a still liquid during short periods of exposure. Transactions of the Amerixan Institute of Chemical Engineers 35, 36-60.##
Hinze, J. O. (1959). Turbulence. McGraw Hill, UK.##
Hunt, J. C. R. (1984). Turbulence structure and tur-bulent diffusion near gas-liquid interfaces. In W. Brutsaert and G. H. Jirka (Eds.), Gas Transfer at Water Surfaces. Water Science and Technology Library, 2, 67-82. Springer, Dordrecht.##
Jähne, B. (2020). Struktur und chaos: kleinskalige austauschprozesse zwischen atmosphäre und meer. In J. Funke and M. Wink (eds.), Entwicklung Wie aus Prozessen Strukturen warden. Heidelberger Jahrbücher Online HDJBO (5), 195-218,##
Jähne, B. and H. Haussecker (1998). Air-water gas exchange. Annual Review of Fluid Mechanics 30(1), 443-468.##
Janzen, J. G. (2006). Gas Transfer Near the Air-Water Interface in Oscillating-Grid Tanks and Properties of Isotropic Turbulent Flows (in Portuguese). M. Sc. Thesis, University of São Paulo, Brazil.  ##
Janzen, J. G., H. Herlina, G. H. Jirka, H. E. Schulz and J. S. Gulliver (2010a). Estimation of mass transfer velocity based on measured turbulence parameters. AIChE Journal 56(8), 2005-2017.##
Janzen, J. G., H. E. Schulz and G. H. Jirka (2010b). Turbulent gas flux measurements near the air–water interface in an oscillating-grid tank. In S. Komori, W. McGillis and R. Kurose (Eds.), Gas Transfer at Water Surfaces, 65-77, Kyoto, Japan.##
Jorgensen, S. E. and M. J. Gromiec (1989). Mathematical submodels in water quality systems: Reaeration. Developments in Environmental Modelling 14, 33-64.##
Lacassagne, T., M. El-Hajem, F. Morge, S. Simoëns and J. Y. Champagne (2017a). Study of gas liquid mass transfer in a grid stirred tank. Oil & Gas Science and Technology 72(7), 1-16.##
Lacassagne, T., M. El Hajem, S. Simoëns and J. Y. Champagne (2017b). In Experimental study of gas-liquid mass transfer enhanced by oscillating grid turbulence, 23ème Congrès Français de Mécanique, Lille.##
Lamont, J. C. and D. S. Scott (1970). An eddy cell model of mass transfer into the surface of a turbulent liquid. AIChE Journal 16(4), 513-519.##
Lavín, F. A. L. (2020). Theoretical Study of the Turbulent Mass Transfer Through Free Surfaces Using Random Square Waves. Ph. D. Thesis, University of São Paulo, Brazil.##
Lavín, F. A. L. and H. E. Schulz (2019). Mass transfer through free surface boundary layers using a statistical approach. WIT Transactions on Engineering Sciences 123, 77-88.##
Lewis, W. K. and W. G. Whitman (1924). Principles of gas absorption. Industrial and Engineering Chemistry 16, 1215-1220.##
Lopes Jr., G. B. (2012). Organizing Statistical Equa-Tions of Mass Transfer in Turbulent Processes. M. Sc. Thesis, University of São Paulo, Brazil.##
Luk, S. and Y. H. Lee (1986). Mass transfer in eddies close to air-water interface. AIChE Journal 32(9), 1546-1554.##
Mackinnon, P. A.; T. Elliot, Y. Q. Zhao, J. L. Murphy and R. M. Kalin (2002). Evaluation of a novel technique for measuring reaeration in rivers. In C. A. Brebbia and P. Zannetti (Eds.), Development and Application of Computer Techniques to Environmental Studies, WIT Press, UK.##
Magnaudet, J. and I. Calmet (2006). Turbulent mass transfer through a flat shear-free surface. Journal of Fluid Mechanics 553, 155-185.##
McCorquodale, M. and R. J. Munro (2017). Experimental study of oscillating-grid turbulence interacting with a solid boundary. Journal of Fluid Mechanics 813, 768-798.##
McCready, M. J., E. Vassiliadou and T. J. Hanratty (1986). Computer simulation of turbulent mass transfer at a mobile interface. AIChE Journal 32(7), 1108-1115.##
Rodi, W. (2000). Turbulence Models and Their Application in Hydraulics A State-of-the-Art Review. IAHR, International Association of Hydraulic Research, Monograph Series.##
Schulz, H. E. (1985). Investigating the Reoxigenation Mechanism of Flowing Waters and Its Relation with the Turbulence Level Close to the Surface - 1. M. Sc. Thesis, University of São Paulo, Brazil.##
Schulz, H. E. and S. A. G. Schulz (1991). Modelling below surface characteristics in water reaeration. In L. C. Wrobel and C. A. Brebbia (Eds.), Water Pollution: Modelling, Measuring and Prediction, 441-454. Springer, Dordrecht.##
Schulz, H. E. and J. G. Janzen (2009). Concentration fields near air-water interfaces during interfacial mass transport: oxygen transport and random square wave analysis. Brazilian Journal of Chemical Engineering 26(3), 527-536.##
Schulz, H. E., A. L. A. Simões and J. G. Janzen (2010). Statistical approximations in gas-liquid mass transfer. In S. Komori, W. McGillisa and R. Kurose (Eds.), Gas Transfer at Water Surfaces, 208-221, Kyoto, Japan.##
Schulz, H. E., G. B. Lopes Jr, A. L. A. Simões and R. J. Lobosco (2011). One dimensional turbulent transfer using random square waves–scalar/ velocity and velocity/velocity interactions. In H. E. Schulz., A. L. A. Simões and R. J. Lobosco (Eds.), Hydrodynamics-Advanced Topics, 3-34, Intech.##
Schulz, H. E. and B. B. Gonçalves (2015) Solutions of scalar mean profiles close to gas-liquid inter-faces under turbulent free slip motion. WIT Transactions on Engineering Sciences 89, 33-44.##
Schulz, H. E.; F. A. L. Lavín and B. B. Gonçalves (2018). Turbulence aspects of mass transfer in the thin interfacial region of the concentration boundary layer in gas–liquid systems. International Journal of Computational Methods and Experimental Measurements 6(1), 186-197.##
Schulz, H. E. (2022). Differential equation for turbulence power losses and energy spectra based on consolidated empirical results. Journal of Applied Fluid Mechanics 15 (4), 959-972.##
Tamburrino, A. and J. S. Gulliver (2002). Free‐surface turbulence and mass transfer in a channel flow. AIChE Journal 48(12), 2732-2743.##
Theofanous, T. G. (1984). Conceptual models of gas exchange. In W. Brutsaert and G. H. Jirka (Eds.), Gas Transfer at Water Surfaces. Water Science and Technology Library, 2, 271-281. Springer, Dordrecht.##
Toor, H. L. and J. M. Marchello (1958) Film-penetration model for mass and heat transfer. AIChE Journal (4), 97-101.##
Turney, D. E. and S. Banerjee (2013). Air–water gas transfer and near-surface motions. Journal of Fluid Mechanics 733, 588-624.##
Wanninkhof, R., W. E. Asher, D. T. Ho, C. Sweeney and W. R. McGillis (2009). Advances in quantifying air-sea gas exchange and environmental forcing. Annual Review of Marine Sciences 1, 213-244.##